How does Ozone work in Wastewater Treatment?
The wastewater treatment process requires a potent agent. In this article you’ll see how Ozone can treat even wastewater, eliminating virus, bacteria, protozoa and many other microorganisms, reducing the use of chemicals, and leaving the process more environmentally friendly.
And how can Ozone act in the wastewater treatment system? Learn as you read below!
In the last 20 years, humans are more exposed to wastewater discharged into the environment.
Ozonization is an emerging technology for disinfection and removing of micropollutants present in the wastewater.
Because ozone is a highly disinfecting and oxidizing agent, many municipalities and industries prefer this advantage technology to treat wastewater.
The application of ozone in the wastewater became more and more popular because it is a reliable process.
How does it work?
The primary mechanism for the destruction of pathogenic organisms to prevent the spread of waterborne diseases is disinfection and ozone is considered, for many studies, the most powerful disinfecting and oxidizing agent.
Ozone is a powerful oxidant and is capable of oxidative degradation of many organic and inorganic compounds. Ozonation degrades efficiently most of the micropollutants present in the wastewater.
Ozone is soluble in water and it decomposes to oxygen, leaves no residual harmful product, no sludge disposal problem and increases the dissolved oxygen (DO) content of wastewater, which helps further in the degradation of residual pollutant.
It is a powerful disinfectant, too. Ozone does not produce any secondary pollutants as compared to chlorine which produces THM, chloramines that are carcinogenic in nature.
A faster ozone reaction means shorter contact time. The reactions with viruses are rapid and there is no risk and toxicity and odor problems.
Ozone is effective 25 times more than hypochlorous acid, 2500 times more than hypochlorite and 5,000 times more than chloramines. All these excellent properties have made ozonization more and more applicative in different fields of wastewater and drinking water treatment.
Ozonation, which is utilized in advanced treatment of secondary wastewater effluent and has shown potential as a means of peroxidising and disinfecting primary wastewater effluents, appears promising in this regard. Recent studies have shown that relatively low ozone (O3) doses (e5 mg/L) can yield >90% depletion of many antibacterial compounds in wastewaters.
Ozone eliminates the following microorganisms that are present in wastewater:
ORGANISM | DISEASE CAUSED |
---|---|
| |
Escherichia coli (enterotoxigenic) | Gastroenteritis |
Leptospira (spp.) | Leptospirosis |
Salmonella typhi | Typhoid fever |
Salmonella (2,100 serotypes) | Salmonellosis |
Shigella(4 spp.) | Shigellosis (bacillary dysentery) |
Vibrio cholerae | Cholera |
| |
Balantidium coli | Balantidiasis |
Cryptospodidium parvum | Cryptosporidiosis |
Entamoeba histolytica | Amebiasis (amoebic dysentery) |
Giardia lamblia elminths | Giardiasis |
Ascaris lumbricoides | Ascariasis |
T.solium | Taeniasis |
Trichuris trichiura | Trichuriasis |
| |
Enteroviruses (72 types, e.g., polio, echo and coxsackie viruses) | Gastroenteritis, heart anomalies, meningitis |
Hepatitis A Virus | Infectious hepatitis |
Norwalk Agent | Gastroenteritis |
Rotavirus | Gastroenteritis |
Some specific compounds oxidized by ozone:
Ammonia | Tannic acids (plants-originated accids) | Amoebae | Spores of Molds |
Phenolics | Sulfides | 2.4 D | Dioxines |
Detergents | Cyanides | Arsenic | |
Fulvic | DDT | Clorine and its derivatives |
Ozone use
Ozone is used to treat a wide variety of wastewater including:
Municipals
Paper industries
Textile industries
Meat processing
Animal waste treatment
Septic
Cutting fluids recycling
Chicken egg processing effluent
Laundry water recycling
Ozone is increasingly used, in combination with other treatments, for eliminating all traces of harmful substances. The advantage here is that ozone treatment does not require the use of additive products, which may prove toxic.
To apply conventional purification techniques first and follow up with ozonation as a second stage, it is advised by many researchers. Thus, ozone is increasingly used as final treatment stage for eliminating all traces of harmful substances.
The effectiveness of disinfection depends on the susceptibility of the target organisms, the contact time, and the concentration of ozone.
All its properties have made ozone as an ultimate treatment for all types of wastewater treatment.
Benefits
Ozone is an effective disinfectant and kills bacteria and virus;
Oxidation of wastewater with ozone has several advantages as increasing dissolved oxygen, reducing chemical consumption, and decreasing turbidity and color;
There are no harmful residuals that need to be removed after ozone treatment because it decomposes rapidly;
Ozone acts as an effective deodorizer and will remove unpleasant or chemicals odors from treated water;
After ozonization, there is no regrowth of microorganisms;
Ozone eliminates heavy metals from wastewater;
Ozone eliminates phenols (coking plant, oil refineries, petrochemical plant, mines, chemical and pharmaceutical process lines, foodstuff, …);
Ozone is a natural, environmentally friendly disinfectant to which no microorganisms can build immunity;
In contrast to chlorine, ozone has an effect on Cryptosporidium P...
Scientific Articles
EMMANUEL I. EPELLE, ANDREW MACFARLANE, MICHAEL CUSACK, ANTHONY BURNS, JUDE A. OKOLIE, WILLIAM MACKAY, MOSTAFA RATEB, MOHAMMED YASEEN | February 15th | Ozone application in different industries: A review of recent developments
LAPO RENAI, MASSIMO DEL BUBBA, AFSANE CHAVOSHANI, SURESH C. AMETA, FABIO BACCI, PABLO CAMPO & OTHERS | 2020 | Micropollutant
XIANPING LUO, QUN YAN, CHUNYING WANG, CAIGUI LUO, NANA ZHOU, CHENSHENG JIAN | September 23rd | Treatment of Ammonia Nitrogen Wastewater in Low Concentration by Two-Stage Ozonization
J. MORILLO ESPARZA, N. CEVALLOS CUEVA, C. SANDOVAL PAUKER, P. VARGAS JENTZSCH, F. MUÑOZ BISESTI | 2019 | Combined treatment using ozone for cyanide removal from wastewater: a comparison
CHAO-HAI WEI, ZHANG FENGZHEN, YUN HU, CHUNHUA FENG | February | Ozonation in water treatment: The generation, basic properties of ozone and its practical application
CLEMENS VON ONNTAG, URS VON GUNTEN | 2012 | Chemistry of Ozone in Water and Wastewater Treatment
MARÍA NEFTALÍ ROJAS-VALENCIA | December | Research on Ozone Application as Disinfectant and Action Mechanisms on Wastewater Microorganisms
JONAS MARGOT, ANOYS MAGNET, DENIS THONNEY, NATHALIE CÈVRE, FELIPPE DE ALENCASTRO, CORNELIA KIENLE, CHRISTIAN ABEGGLEN, DAVID ANDREW BARRY, LUCA ROSSI | May | Elimination of micropollutants in wastewater treatment plants : Ozonation or activated carbon? Conclusions of a one-year pilot project
R. EL ARABY, S. HAWASH, G. EL DIWANI | December 25th | Treatment of iron and manganese in simulated groundwater via ozone technology
WANG BAOZHEN, TIAN JINZHI, YIN JUN, SHI GUANGMEI | July 23rd | Ammonia, Nitrite and Nitrate Nitrogen Removal from Polluted Source Water with Ozonation and BAC Processes
A. RODRÍGUEZ, ROBERTO ROSAL, JOSE A. PERDIGÓN-MELÓN, M. MEZCUA | July | Ozone-Based Technologies in Water and Wastewater Treatment
MIICHAEL C. DODD, MARC-OLIVIER BUFFLE, URS VON GUNTEN | February 7th | Oxidation of Antibacterial Molecules by Aqueous Ozone: Moiety-Specific Reaction Kinetics and Application to Ozone-Based Wastewater Treatment
F. NAVA, U. URIBE, R. PÉREZ | March 15th | Use of ozone in the treatment of cyanide containing effluents
US EPA (United States Environmental Protection Agency) – OFFICE OF WATER WASHINGTON D.C. | October | Proven Alternatives for Aboveground Treatment of Arsenic in Groundwater
PEI XU, MARIE-LAURE JANEX, PHILIPPE SAVOYE, ARNOLD COCKX, VALENTINA LAZAROVA | February | Wastewater disinfection by ozone: main parameters for process design
JAMES A. MUELLER, WILLIAM C. BOYLE, H. JOHANNES PÖPEL | 2002 | AERATION: Principles and Practice
US EPA (United States Environmental Protection Agency) – OFFICE OF WATER WASHINGTON D.C. | September | Wastewater Technology Fact Sheet – Ozone Disinfection
US EPA (United States Environmental Protection Agency) – OFFICE OF WATER WASHINGTON D.C. | September | Wastewater Technology Fact Sheet – Fine Bubble Aeration
Y. MAGARA, M- ITOH, T. MORIOKA | 1995 | Application of ozone to water treatment and power consumption of ozone generating systems
ITALY – Health Ministry | Scientific Validations of Ozone Use